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Gay Head cliffs in "Martha's Vineyard consist almost entirely of clay.

Clay is a finely-grained natural "rock or "soil material that combines one or more "clay minerals with traces of "metal oxides and "organic matter. Geologic clay "deposits are mostly composed of "phyllosilicate minerals containing variable amounts of "water trapped in the mineral structure. Clays are "plastic due to that water content and become hard, brittle and non–plastic upon drying or "firing.[1][2][3] "Depending on the soil's content in which it is found, clay can appear in various colours from white to dull grey or brown to deep orange-red.

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Electron microscope photograph of smectite clay – magnification 23,500

Although many naturally occurring deposits include both silts and clay, clays are distinguished from other fine-grained soils by differences in size and mineralogy. "Silts, which are fine-grained soils that do not include clay minerals, tend to have larger particle sizes than clays. There is, however, some overlap in particle size and other physical properties. The distinction between silt and clay varies by discipline. "Geologists and "soil scientists usually consider the separation to occur at a particle size of 2 "µm (clays being finer than silts), "sedimentologists often use 4–5 μm, and "colloid "chemists use 1 μm.[1] "Geotechnical engineers distinguish between silts and clays based on the plasticity properties of the soil, as measured by the soils' "Atterberg limits. ISO 14688 grades clay particles as being smaller than 2 μm and silt particles as being larger.

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"Quaternary clay in "Estonia

Contents

Formation[edit]

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Deforestation for clay extraction in "Rio de Janeiro, "Brazil. The picture is of Morro da Covanca, Jacarepaguá.

Clay minerals typically form over long periods of time as a result of the gradual chemical "weathering of rocks, usually silicate-bearing, by low concentrations of "carbonic acid and other diluted "solvents. These solvents, usually acidic, migrate through the weathering rock after "leaching through upper weathered layers. In addition to the weathering process, some clay minerals are formed through "hydrothermal activity. There are two types of clay deposits: primary and secondary. Primary clays form as residual deposits in soil and remain at the site of formation. Secondary clays are clays that have been transported from their original location by water erosion and "deposited in a new "sedimentary deposit.[4] Clay deposits are typically associated with very low energy "depositional environments such as large lakes and marine basins.

Grouping[edit]

Depending on the academic source, there are three or four main groups of clays: "kaolinite, "montmorillonite-"smectite, "illite, and "chlorite. Chlorites are not always considered to be a clay, sometimes being classified as a separate group within the "phyllosilicates. There are approximately 30 different types of "pure" clays in these categories, but most "natural" clay deposits are mixtures of these different types, along with other weathered minerals.

"Varve (or varved clay) is clay with visible annual layers, which are formed by seasonal deposition of those layers and are marked by differences in "erosion and organic content. This type of "deposit is common in former "glacial lakes. When fine sediments are delivered into the calm waters of these glacial lake basins away from the shoreline, they settle to the lake bed. The resulting seasonal layering is preserved in an even distribution of clay sediment banding.[4]

"Quick clay is a unique type of "marine clay indigenous to the glaciated terrains of "Norway, "Canada, "Northern Ireland, and "Sweden. It is a highly sensitive clay, prone to "liquefaction, which has been involved in several deadly "landslides.

Historical and modern uses[edit]

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Clay layers in a construction site. Dry clay is normally much more stable than sand with regard to excavations.

Clays exhibit "plasticity when mixed with water in certain proportions. However, when dry, clay becomes firm and when "fired in a "kiln, permanent physical and chemical changes occur. These changes convert the clay into a "ceramic material. Because of these properties, clay is used for making "pottery, both utilitarian and decorative, and construction products, such as bricks, wall and floor tiles. Different types of clay, when used with different "minerals and firing conditions, are used to produce "earthenware, "stoneware, and "porcelain. "Prehistoric humans discovered the useful properties of clay. Some of the earliest pottery shards recovered are from central "Honshu, "Japan. They are associated with the "Jomon culture and deposits they were recovered from have been "dated to around 14,000 BC.[5]

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"Bottle stopper made of clay, 14th century

Clay tablets were the first known writing medium.[6] Scribes wrote by inscribing them with "cuneiform script using a blunt "reed called a "stylus. Purpose-made clay balls were also used as "sling ammunition.

Clays "sintered in fire were the first form of "ceramic. "Bricks, cooking pots, art objects, "dishware, and even "musical instruments such as the "ocarina can all be shaped from clay before being fired. Clay is also used in many industrial processes, such as "paper making, "cement production, and chemical "filtering. Clay is also often used in the manufacture of "pipes for smoking "tobacco. Until the late 20th century, "bentonite clay was widely used as a mold binder in the manufacture of "sand castings.

Clay, being relatively "impermeable to water, is also used where natural seals are needed, such as in the cores of "dams, or as a barrier in "landfills against toxic seepage (lining the landfill, preferably in combination with "geotextiles).[7] (See "puddling.)

Studies in the early 21st century have investigated clay's "absorption capacities in various applications, such as the removal of "heavy metals from waste water and air purification.[8][9]

Medicinal uses[edit]

Traditional uses of "clay as medicine go back to prehistoric times. An example is "Armenian bole, which is used to soothe an upset "stomach, similar to the way "parrots (and later, humans) in "South America originally used clay.[10] "Kaolin clay and "attapulgite have been used as anti-diarrheal medicines.

As a building material[edit]

Clay is one of the oldest building materials on "Earth, among other ancient, naturally-occurring geologic materials such as "stone and organic materials like "wood.[11] Between one-half and two-thirds of the world's population, in both traditional societies as well as developed countries, still live or work in buildings made with clay, often baked into "brick, as an essential part of its load-bearing structure. Also a primary ingredient in many "natural building techniques, clay is used to create "adobe, "cob, "cordwood, and "rammed earth structures and building elements such as "wattle and daub, clay plaster, clay render case, clay floors and clay "paints and "ceramic building material. Clay was used as a "mortar in brick "chimneys and stone walls where protected from water.

See also[edit]

Footnotes[edit]

  1. ^ a b Guggenheim & Martin 1995, pp. 255–256
  2. ^ "University College London Geology on Campus: Clays". Earth Sciences department. "University College London. Retrieved 10 January 2016. 
  3. ^ "What is clay". Science Learning Hub. "University of Waikato. Retrieved 10 January 2016. 
  4. ^ a b "Environmental Characteristics of Clays and Clay Mineral Deposits". usgs.gov. 
  5. ^ Scarre, C. 2005. The Human Past, Thames and Hudson: London, p.238
  6. ^ Ebert, John David (2011-08-31). The New Media Invasion: Digital Technologies and the World They Unmake. McFarland. "ISBN "9780786488186. 
  7. ^ Koçkar, Mustafa K.; Akgün, Haluk; Aktürk, Özgür, Preliminary evaluation of a compacted bentonite / sand mixture as a landfill liner material (Abstract). Department of Geological Engineering, "Middle East Technical University, "Ankara, "Turkey
  8. ^ García-Sanchez, A.; Alvarez-Ayuso, E.; Rodriguez-Martin, F. (2002-03-01). "Sorption of As(V) by some oxyhydroxides and clay minerals. Application to its immobilization in two polluted mining soils". Clay Minerals. 37 (1): 187–194. "doi:10.1180/0009855023710027. 
  9. ^ Churchman, G. J.; Gates, W. P.; Theng, B. K. G.; Yuan, G. (2006). Faïza Bergaya, Benny K. G. Theng and Gerhard Lagaly, ed. "Chapter 11.1 Clays and Clay Minerals for Pollution Control". Developments in Clay Science. Handbook of Clay Science. Elsevier. 1: 625–675. "doi:10.1016/S1572-4352(05)01020-2. 
  10. ^ DIAMOND, JARED M. "Diamond on Geophagy". ucla.edu. 
  11. ^ Grim, Ralph. "Clay mineral". "Encyclopædia Britannica. Retrieved 10 January 2016. 

References[edit]

External links[edit]

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