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In "nuclear physics and "nuclear chemistry, nuclear fission is either a "nuclear reaction or a "radioactive decay process in which the "nucleus of an atom splits into smaller parts (lighter "nuclei). The fission process often produces free "neutrons and "gamma "photons, and releases a very large amount of "energy even by the energetic standards of radioactive decay.
Nuclear fission of heavy elements was discovered on December 17, 1938 by German "Otto Hahn and his assistant "Fritz Strassmann, and explained theoretically in January 1939 by "Lise Meitner and her nephew "Otto Robert Frisch. Frisch named the process by analogy with "biological fission of living cells. It is an "exothermic reaction which can release large amounts of "energy both as "electromagnetic radiation and as "kinetic energy of the fragments ("heating the bulk material where fission takes place). In order for fission to produce energy, the total "binding energy of the resulting elements must be less negative (higher energy) than that of the starting element.
Fission is a form of "nuclear transmutation because the resulting fragments are not the same "element as the original atom. The two nuclei produced are most often of comparable but slightly different sizes, typically with a mass ratio of products of about 3 to 2, for common "fissile "isotopes. Most fissions are binary fissions (producing two charged fragments), but occasionally (2 to 4 times per 1000 events), three positively charged fragments are produced, in a "ternary fission. The smallest of these fragments in ternary processes ranges in size from a proton to an "argon nucleus.
Apart from fission induced by a neutron, harnessed and exploited by humans, a natural form of spontaneous "radioactive decay (not requiring a neutron) is also referred to as fission, and occurs especially in very high-mass-number isotopes. "Spontaneous fission was discovered in 1940 by "Flyorov, "Petrzhak and "Kurchatov in Moscow, when they decided to confirm that, without bombardment by neutrons, the fission rate of uranium was indeed negligible, as predicted by "Niels Bohr; it was not.
The unpredictable composition of the products (which vary in a broad probabilistic and somewhat chaotic manner) distinguishes fission from purely quantum-tunneling processes such as "proton emission, "alpha decay, and "cluster decay, which give the same products each time. Nuclear fission produces energy for "nuclear power and drives the explosion of "nuclear weapons. Both uses are possible because certain substances called "nuclear fuels undergo fission when struck by fission neutrons, and in turn emit neutrons when they break apart. This makes possible a self-sustaining "nuclear chain reaction that releases energy at a controlled rate in a "nuclear reactor or at a very rapid uncontrolled rate in a "nuclear weapon.
The amount of "free energy contained in nuclear fuel is millions of times the amount of free energy contained in a similar mass of chemical fuel such as "gasoline, making nuclear fission a very dense source of energy. The products of nuclear fission, however, are on average far more "radioactive than the heavy elements which are normally fissioned as fuel, and remain so for significant amounts of time, giving rise to a "nuclear waste problem. Concerns over "nuclear waste accumulation and over the "destructive potential of nuclear weapons are a counterbalance to the peaceful desire to use "fission as an energy source, and give rise to ongoing "political "debate over "nuclear power.
Nuclear fission can occur without "neutron bombardment as a type of "radioactive decay. This type of fission (called "spontaneous fission) is rare except in a few heavy isotopes. In engineered nuclear devices, essentially all nuclear fission occurs as a ""nuclear reaction" — a bombardment-driven process that results from the collision of two subatomic particles. In nuclear reactions, a subatomic particle collides with an atomic nucleus and causes changes to it. Nuclear reactions are thus driven by the mechanics of bombardment, not by the relatively constant "exponential decay and "half-life characteristic of spontaneous radioactive processes.
Many types of "nuclear reactions are currently known. Nuclear fission differs importantly from other types of nuclear reactions, in that it can be amplified and sometimes controlled via a "nuclear chain reaction (one type of general "chain reaction). In such a reaction, free "neutrons released by each fission event can trigger yet more events, which in turn release more neutrons and cause more fissions.
The "chemical element "isotopes that can sustain a fission chain reaction are called "nuclear fuels, and are said to be "fissile. The most common nuclear fuels are "235U (the isotope of "uranium with an "atomic mass of 235 and of use in nuclear reactors) and "239Pu (the isotope of "plutonium with an "atomic mass of 239). These fuels break apart into a bimodal range of chemical elements with atomic masses centering near 95 and 135 u ("fission products). Most nuclear fuels undergo "spontaneous fission only very slowly, decaying instead mainly via an "alpha-"beta "decay chain over periods of "millennia to "eons. In a "nuclear reactor or nuclear weapon, the overwhelming majority of fission events are induced by bombardment with another particle, a neutron, which is itself produced by prior fission events.
Nuclear fissions in fissile fuels are the result of the nuclear excitation energy produced when a fissile nucleus captures a neutron. This energy, resulting from the neutron capture, is a result of the attractive "nuclear force acting between the neutron and nucleus. It is enough to deform the nucleus into a double-lobed "drop," to the point that nuclear fragments exceed the distances at which the nuclear force can hold two groups of charged nucleons together and, when this happens, the two fragments complete their separation and then are driven further apart by their mutually repulsive charges, in a process which becomes irreversible with greater and greater distance. A similar process occurs in "fissionable isotopes (such as uranium-238), but in order to fission, these isotopes require additional energy provided by "fast neutrons (such as those produced by "nuclear fusion in "thermonuclear weapons).
The "liquid drop model of the "atomic nucleus predicts equal-sized fission products as an outcome of nuclear deformation. The more sophisticated "nuclear shell model is needed to mechanistically explain the route to the more energetically favorable outcome, in which one fission product is slightly smaller than the other. A theory of the fission based on shell model has been formulated by "Maria Goeppert Mayer.
The most common fission process is binary fission, and it produces the fission products noted above, at 95±15 and 135±15 u. However, the binary process happens merely because it is the most probable. In anywhere from 2 to 4 fissions per 1000 in a nuclear reactor, a process called "ternary fission produces three positively charged fragments (plus neutrons) and the smallest of these may range from so small a charge and mass as a proton (Z=1), to as large a fragment as "argon (Z=18). The most common small fragments, however, are composed of 90% helium-4 nuclei with more energy than alpha particles from alpha decay (so-called "long range alphas" at ~ 16 MeV), plus helium-6 nuclei, and tritons (the nuclei of "tritium). The ternary process is less common, but still ends up producing significant helium-4 and tritium gas buildup in the fuel rods of modern nuclear reactors.
The fission of a heavy nucleus requires a total input energy of about 7 to 8 million "electron volts (MeV) to initially overcome the "nuclear force which holds the nucleus into a spherical or nearly spherical shape, and from there, deform it into a two-lobed ("peanut") shape in which the lobes are able to continue to separate from each other, pushed by their mutual positive charge, in the most common process of binary fission (two positively charged fission products + neutrons). Once the nuclear lobes have been pushed to a critical distance, beyond which the short range "strong force can no longer hold them together, the process of their separation proceeds from the energy of the (longer range) "electromagnetic repulsion between the fragments. The result is two fission fragments moving away from each other, at high energy.
About 6 MeV of the fission-input energy is supplied by the simple binding of an extra neutron to the heavy nucleus via the strong force; however, in many fissionable isotopes, this amount of energy is not enough for fission. Uranium-238, for example, has a near-zero fission cross section for neutrons of less than one MeV energy. If no additional energy is supplied by any other mechanism, the nucleus will not fission, but will merely absorb the neutron, as happens when U-238 absorbs slow and even some fraction of fast neutrons, to become U-239. The remaining energy to initiate fission can be supplied by two other mechanisms: one of these is more kinetic energy of the incoming neutron, which is increasingly able to fission a "fissionable heavy nucleus as it exceeds a kinetic energy of one MeV or more (so-called "fast neutrons). Such high energy neutrons are able to fission U-238 directly (see "thermonuclear weapon for application, where the fast neutrons are supplied by "nuclear fusion). However, this process cannot happen to a great extent in a nuclear reactor, as too small a fraction of the fission neutrons produced by any type of fission have enough energy to efficiently fission U-238 (fission neutrons have a "mode energy of 2 MeV, but a "median of only 0.75 MeV, meaning half of them have less than this insufficient energy).
Among the heavy actinide elements, however, those isotopes that have an odd number of neutrons (such as U-235 with 143 neutrons) bind an extra neutron with an additional 1 to 2 MeV of energy over an isotope of the same element with an even number of neutrons (such as U-238 with 146 neutrons). This extra binding energy is made available as a result of the mechanism of "neutron pairing effects. This extra energy results from the "Pauli exclusion principle allowing an extra neutron to occupy the same nuclear orbital as the last neutron in the nucleus, so that the two form a pair. In such isotopes, therefore, no neutron kinetic energy is needed, for all the necessary energy is supplied by absorption of any neutron, either of the slow or fast variety (the former are used in moderated nuclear reactors, and the latter are used in "fast neutron reactors, and in weapons). As noted above, the subgroup of fissionable elements that may be fissioned efficiently with their own fission neutrons (thus potentially causing a nuclear "chain reaction in relatively small amounts of the pure material) are termed ""fissile." Examples of fissile isotopes are U-235 and plutonium-239.
Typical fission events release about two hundred million "eV (200 MeV) of energy for each fission event. The exact isotope which is fissioned, and whether or not it is fissionable or fissile, has only a small impact on the amount of energy released. This can be easily seen by examining the curve of "binding energy (image below), and noting that the average binding energy of the "actinide nuclides beginning with uranium is around 7.6 MeV per nucleon. Looking further left on the curve of binding energy, where the "fission products cluster, it is easily observed that the binding energy of the fission products tends to center around 8.5 MeV per nucleon. Thus, in any fission event of an isotope in the actinide's range of mass, roughly 0.9 MeV is released per nucleon of the starting element. The fission of U235 by a slow neutron yields nearly identical energy to the fission of U238 by a fast neutron. This energy release profile holds true for thorium and the various minor actinides as well.
By contrast, most "chemical "oxidation reactions (such as burning "coal or "TNT) release at most a few "eV per event. So, nuclear fuel contains at least ten million times more "usable energy per unit mass than does chemical fuel. The energy of nuclear fission is released as "kinetic energy of the fission products and fragments, and as "electromagnetic radiation in the form of "gamma rays; in a nuclear reactor, the energy is converted to "heat as the particles and gamma rays collide with the atoms that make up the reactor and its "working fluid, usually "water or occasionally "heavy water or "molten salts.
When a "uranium nucleus fissions into two daughter nuclei fragments, about 0.1 percent of the mass of the uranium nucleus appears as the fission energy of ~200 MeV. For uranium-235 (total mean fission energy 202.5 MeV), typically ~169 MeV appears as the "kinetic energy of the daughter nuclei, which fly apart at about 3% of the speed of light, due to "Coulomb repulsion. Also, an average of 2.5 neutrons are emitted, with a "mean kinetic energy per neutron of ~2 MeV (total of 4.8 MeV). The fission reaction also releases ~7 MeV in prompt "gamma ray "photons. The latter figure means that a nuclear fission explosion or criticality accident emits about 3.5% of its energy as gamma rays, less than 2.5% of its energy as fast neutrons (total of both types of radiation ~ 6%), and the rest as kinetic energy of fission fragments (this appears almost immediately when the fragments impact surrounding matter, as simple "heat). In an atomic bomb, this heat may serve to raise the temperature of the bomb core to 100 million "kelvin and cause secondary emission of soft X-rays, which convert some of this energy to ionizing radiation. However, in nuclear reactors, the fission fragment kinetic energy remains as low-temperature heat, which itself causes little or no ionization.
So-called "neutron bombs (enhanced radiation weapons) have been constructed which release a larger fraction of their energy as ionizing radiation (specifically, neutrons), but these are all thermonuclear devices which rely on the nuclear fusion stage to produce the extra radiation. The energy dynamics of pure fission bombs always remain at about 6% yield of the total in radiation, as a prompt result of fission.
The total prompt fission energy amounts to about 181 MeV, or ~ 89% of the total energy which is eventually released by fission over time. The remaining ~ 11% is released in beta decays which have various half-lives, but begin as a process in the fission products immediately; and in delayed gamma emissions associated with these beta decays. For example, in uranium-235 this delayed energy is divided into about 6.5 MeV in betas, 8.8 MeV in "antineutrinos (released at the same time as the betas), and finally, an additional 6.3 MeV in delayed gamma emission from the excited beta-decay products (for a mean total of ~10 gamma ray emissions per fission, in all). Thus, about 6.5% of the total energy of fission is released some time after the event, as non-prompt or delayed ionizing radiation, and the delayed ionizing energy is about evenly divided between gamma and beta ray energy.
In a reactor that has been operating for some time, the radioactive fission products will have built up to steady state concentrations such that their rate of decay is equal to their rate of formation, so that their fractional total contribution to reactor heat (via beta decay) is the same as these radioisotopic fractional contributions to the energy of fission. Under these conditions, the 6.5% of fission which appears as delayed ionizing radiation (delayed gammas and betas from radioactive fission products) contributes to the steady-state reactor heat production under power. It is this output fraction which remains when the reactor is suddenly shut down (undergoes "scram). For this reason, the reactor "decay heat output begins at 6.5% of the full reactor steady state fission power, once the reactor is shut down. However, within hours, due to decay of these isotopes, the decay power output is far less. See "decay heat for detail.
The remainder of the delayed energy (8.8 MeV/202.5 MeV = 4.3% of total fission energy) is emitted as antineutrinos, which as a practical matter, are not considered "ionizing radiation." The reason is that energy released as antineutrinos is not captured by the reactor material as heat, and escapes directly through all materials (including the Earth) at nearly the speed of light, and into interplanetary space (the amount absorbed is minuscule). Neutrino radiation is ordinarily not classed as ionizing radiation, because it is almost entirely not absorbed and therefore does not produce effects (although the very rare neutrino event is ionizing). Almost all of the rest of the radiation (6.5% delayed beta and gamma radiation) is eventually converted to heat in a reactor core or its shielding.
Some processes involving neutrons are notable for absorbing or finally yielding energy — for example neutron kinetic energy does not yield heat immediately if the neutron is captured by a uranium-238 atom to breed plutonium-239, but this energy is emitted if the plutonium-239 is later fissioned. On the other hand, so-called "delayed neutrons emitted as radioactive decay products with half-lives up to several minutes, from fission-daughters, are very important to "reactor control, because they give a characteristic "reaction" time for the total nuclear reaction to double in size, if the reaction is run in a ""delayed-critical" zone which deliberately relies on these neutrons for a supercritical chain-reaction (one in which each fission cycle yields more neutrons than it absorbs). Without their existence, the nuclear chain-reaction would be "prompt critical and increase in size faster than it could be controlled by human intervention. In this case, the first experimental atomic reactors would have run away to a dangerous and messy "prompt critical reaction" before their operators could have manually shut them down (for this reason, designer "Enrico Fermi included radiation-counter-triggered control rods, suspended by electromagnets, which could automatically drop into the center of "Chicago Pile-1). If these delayed neutrons are captured without producing fissions, they produce heat as well.
In fission there is a preference to yield fragments with even proton numbers, which is called the odd-even effect on the fragments' charge distribution. However, no odd-even effect is observed on fragment mass number distribution. This result is attributed to "nucleon pair breaking.
In nuclear fission events the nuclei may break into any combination of lighter nuclei, but the most common event is not fission to equal mass nuclei of about mass 120; the most common event (depending on isotope and process) is a slightly unequal fission in which one daughter nucleus has a mass of about 90 to 100 u and the other the remaining 130 to 140 u. Unequal fissions are energetically more favorable because this allows one product to be closer to the energetic minimum near mass 60 u (only a quarter of the average fissionable mass), while the other nucleus with mass 135 u is still not far out of the range of the most tightly bound nuclei (another statement of this, is that the atomic "binding energy curve is slightly steeper to the left of mass 120 u than to the right of it).
Nuclear fission of heavy elements produces exploitable energy because the specific "binding energy (binding energy per mass) of intermediate-mass nuclei with "atomic numbers and "atomic masses close to 62Ni and 56Fe is greater than the nucleon-specific binding energy of very heavy nuclei, so that energy is released when heavy nuclei are broken apart. The total rest masses of the fission products (Mp) from a single reaction is less than the mass of the original fuel nucleus (M). The excess mass Δm = M – Mp is the "invariant mass of the energy that is released as "photons ("gamma rays) and kinetic energy of the fission fragments, according to the "mass-energy equivalence formula E = mc2.
The variation in specific binding energy with "atomic number is due to the interplay of the two fundamental "forces acting on the component "nucleons ("protons and "neutrons) that make up the nucleus. Nuclei are bound by an attractive "nuclear force between nucleons, which overcomes the "electrostatic repulsion between protons. However, the nuclear force acts only over relatively short ranges (a few "nucleon diameters), since it follows an exponentially decaying "Yukawa potential which makes it insignificant at longer distances. The electrostatic repulsion is of longer range, since it decays by an inverse-square rule, so that nuclei larger than about 12 nucleons in diameter reach a point that the total electrostatic repulsion overcomes the nuclear force and causes them to be spontaneously unstable. For the same reason, larger nuclei (more than about eight nucleons in diameter) are less tightly bound per unit mass than are smaller nuclei; breaking a large nucleus into two or more intermediate-sized nuclei releases energy. The origin of this energy is the nuclear force, which intermediate-sized nuclei allows to act more efficiently, because each nucleon has more neighbors which are within the short range attraction of this force. Thus less energy is needed in the smaller nuclei and the difference to the state before is set free.
Also because of the short range of the strong binding force, large stable nuclei must contain proportionally more neutrons than do the lightest elements, which are most stable with a 1 to 1 ratio of protons and neutrons. Nuclei which have more than 20 protons cannot be stable unless they have more than an equal number of neutrons. Extra neutrons stabilize heavy elements because they add to strong-force binding (which acts between all nucleons) without adding to proton–proton repulsion. Fission products have, on average, about the same ratio of neutrons and protons as their parent nucleus, and are therefore usually unstable to beta decay (which changes neutrons to protons) because they have proportionally too many neutrons compared to stable isotopes of similar mass.
This tendency for fission product nuclei to beta-decay is the fundamental cause of the problem of "radioactive "high level waste from nuclear reactors. Fission products tend to be "beta emitters, "emitting fast-moving "electrons to conserve "electric charge, as excess neutrons convert to protons in the fission-product atoms. See "Fission products (by element) for a description of fission products sorted by element.
Several heavy elements, such as "uranium, "thorium, and "plutonium, undergo both "spontaneous fission, a form of "radioactive decay and induced fission, a form of "nuclear reaction. Elemental isotopes that undergo induced fission when struck by a free "neutron are called "fissionable; isotopes that undergo fission when struck by a slow-moving "thermal neutron are also called "fissile. A few particularly fissile and readily obtainable isotopes (notably 233U, 235U and 239Pu) are called "nuclear fuels because they can sustain a chain reaction and can be obtained in large enough quantities to be useful.
All fissionable and fissile isotopes undergo a small amount of spontaneous fission which releases a few free neutrons into any sample of nuclear fuel. Such neutrons would escape rapidly from the fuel and become a "free neutron, with a "mean lifetime of about 15 minutes before decaying to "protons and "beta particles. However, neutrons almost invariably impact and are absorbed by other nuclei in the vicinity long before this happens (newly created fission neutrons move at about 7% of the speed of light, and even moderated neutrons move at about 8 times the speed of sound). Some neutrons will impact fuel nuclei and induce further fissions, releasing yet more neutrons. If enough nuclear fuel is assembled in one place, or if the escaping neutrons are sufficiently contained, then these freshly emitted neutrons outnumber the neutrons that escape from the assembly, and a sustained nuclear chain reaction will take place.
An assembly that supports a sustained nuclear chain reaction is called a "critical assembly or, if the assembly is almost entirely made of a nuclear fuel, a "critical mass. The word "critical" refers to a "cusp in the behavior of the "differential equation that governs the number of free neutrons present in the fuel: if less than a critical mass is present, then the amount of neutrons is determined by "radioactive decay, but if a critical mass or more is present, then the amount of neutrons is controlled instead by the physics of the chain reaction. The actual "mass of a critical mass of nuclear fuel depends strongly on the geometry and surrounding materials.
Not all fissionable isotopes can sustain a chain reaction. For example, 238U, the most abundant form of uranium, is fissionable but not fissile: it undergoes induced fission when impacted by an energetic neutron with over 1 MeV of kinetic energy. However, too few of the neutrons produced by 238U fission are energetic enough to induce further fissions in 238U, so no chain reaction is possible with this isotope. Instead, bombarding 238U with slow neutrons causes it to absorb them (becoming 239U) and decay by "beta emission to 239Np which then decays again by the same process to 239Pu; that process is used to manufacture 239Pu in "breeder reactors. In-situ plutonium production also contributes to the neutron chain reaction in other types of reactors after sufficient plutonium-239 has been produced, since plutonium-239 is also a fissile element which serves as fuel. It is estimated that up to half of the power produced by a standard "non-breeder" reactor is produced by the fission of plutonium-239 produced in place, over the total life-cycle of a fuel load.
Fissionable, non-fissile isotopes can be used as fission energy source even without a chain reaction. Bombarding 238U with fast neutrons induces fissions, releasing energy as long as the external neutron source is present. This is an important effect in all reactors where fast neutrons from the fissile isotope can cause the fission of nearby 238U nuclei, which means that some small part of the 238U is "burned-up" in all nuclear fuels, especially in fast breeder reactors that operate with higher-energy neutrons. That same fast-fission effect is used to augment the energy released by modern "thermonuclear weapons, by jacketing the weapon with 238U to react with neutrons released by nuclear fusion at the center of the device. But the explosive effects of nuclear fission chain reactions can be reduced by using substances like moderators which slow down the speed of secondary neutrons.
Critical fission reactors are the most common type of "nuclear reactor. In a critical fission reactor, neutrons produced by fission of fuel atoms are used to induce yet more fissions, to sustain a controllable amount of energy release. Devices that produce engineered but non-self-sustaining fission reactions are "subcritical fission reactors. Such devices use "radioactive decay or "particle accelerators to trigger fissions.
Critical fission reactors are built for three primary purposes, which typically involve different engineering trade-offs to take advantage of either the heat or the neutrons produced by the fission chain reaction:
While, in principle, all fission reactors can act in all three capacities, in practice the tasks lead to conflicting engineering goals and most reactors have been built with only one of the above tasks in mind. (There are several early counter-examples, such as the "Hanford "N reactor, now decommissioned). Power reactors generally convert the kinetic energy of fission products into heat, which is used to heat a "working fluid and drive a "heat engine that generates mechanical or electrical power. The working fluid is usually water with a steam turbine, but some designs use other materials such as gaseous "helium. Research reactors produce neutrons that are used in various ways, with the heat of fission being treated as an unavoidable waste product. Breeder reactors are a specialized form of research reactor, with the caveat that the sample being irradiated is usually the fuel itself, a mixture of 238U and 235U. For a more detailed description of the physics and operating principles of critical fission reactors, see "nuclear reactor physics. For a description of their social, political, and environmental aspects, see "nuclear power.
One class of "nuclear weapon, a fission bomb (not to be confused with the "fusion bomb), otherwise known as an atomic bomb or atom bomb, is a fission reactor designed to liberate as much energy as possible as rapidly as possible, before the released energy causes the reactor to explode (and the chain reaction to stop). Development of nuclear weapons was the motivation behind early research into nuclear fission which the "Manhattan Project during "World War II (September 1, 1939 – September 2, 1945) carried out most of the early scientific work on fission chain reactions, culminating in the three events involving fission bombs that occurred during the war. The first fission bomb, codenamed "The Gadget", was detonated during the "Trinity Test in the desert of "New Mexico on July 16, 1945. Two other fission bombs, codenamed ""Little Boy" and ""Fat Man", were used in "combat against the "Japanese cities of "Hiroshima and "Nagasaki in on August 6 and 9, 1945 respectively.
Even the first fission bombs were thousands of times more "explosive than a comparable mass of "chemical explosive. For example, Little Boy weighed a total of about four tons (of which 60 kg was nuclear fuel) and was 11 feet (3.4 m) long; it also yielded an explosion equivalent to about 15 kilotons of "TNT, destroying a large part of the city of Hiroshima. Modern nuclear weapons (which include a thermonuclear fusion as well as one or more fission stages) are hundreds of times more energetic for their weight than the first pure fission atomic bombs (see "nuclear weapon yield), so that a modern single missile warhead bomb weighing less than 1/8 as much as Little Boy (see for example "W88) has a yield of 475,000 tons of TNT, and could bring destruction to about 10 times the city area.
While the fundamental physics of the fission "chain reaction in a nuclear weapon is similar to the physics of a controlled nuclear reactor, the two types of device must be engineered quite differently (see "nuclear reactor physics). A nuclear bomb is designed to release all its energy at once, while a reactor is designed to generate a steady supply of useful power. While overheating of a reactor can lead to, and has led to, "meltdown and "steam explosions, the much lower "uranium enrichment makes it impossible for a "nuclear reactor to explode with the same destructive power as a nuclear weapon. It is also difficult to extract useful power from a nuclear bomb, although at least one "rocket propulsion system, "Project Orion, was intended to work by exploding fission bombs behind a massively padded and shielded spacecraft.
The "strategic importance of nuclear weapons is a major reason why the "technology of nuclear fission is politically sensitive. Viable fission bomb designs are, arguably, within the capabilities of many, being relatively simple from an engineering viewpoint. However, the difficulty of obtaining fissile nuclear material to realize the designs is the key to the relative unavailability of nuclear weapons to all but modern industrialized governments with special programs to produce fissile materials (see "uranium enrichment and nuclear fuel cycle.
The discovery of nuclear fission occurred in 1938 in the buildings of "Kaiser Wilhelm Society for Chemistry, today part of the "Free University of Berlin, following nearly five decades of work on the science of "radioactivity and the elaboration of new "nuclear physics that described the components of "atoms. In 1911, "Ernest Rutherford proposed a model of the atom in which a very small, dense and positively charged "nucleus of "protons (the "neutron had not yet been discovered) was surrounded by orbiting, negatively charged "electrons (the "Rutherford model). "Niels Bohr improved upon this in 1913 by reconciling the quantum behavior of electrons (the "Bohr model). Work by "Henri Becquerel, "Marie Curie, "Pierre Curie, and Rutherford further elaborated that the nucleus, though tightly bound, could undergo different forms of "radioactive decay, and thereby "transmute into other elements. (For example, by "alpha decay: the emission of an "alpha particle—two protons and two neutrons bound together into a particle identical to a "helium nucleus.)
Some work in "nuclear transmutation had been done. In 1917, Rutherford was able to accomplish transmutation of nitrogen into oxygen, using alpha particles directed at nitrogen 14N + α → 17O + p. This was the first observation of a "nuclear reaction, that is, a reaction in which particles from one decay are used to transform another atomic nucleus. Eventually, in 1932, a fully artificial nuclear reaction and nuclear transmutation was achieved by Rutherford's colleagues "Ernest Walton and "John Cockcroft, who used artificially accelerated protons against lithium-7, to split this nucleus into two alpha particles. The feat was popularly known as "splitting the atom", although it was not the modern nuclear fission reaction later discovered in heavy elements, which is discussed below. Meanwhile, the possibility of combining nuclei—"nuclear fusion—had been studied in connection with understanding the processes which power "stars. The first artificial fusion reaction had been achieved by "Mark Oliphant in 1932, using two accelerated "deuterium nuclei (each consisting of a single proton bound to a single neutron) to create a "helium-3 nucleus.
After English physicist "James Chadwick discovered the "neutron in 1932, "Enrico Fermi and his colleagues in "Rome studied the results of bombarding uranium with neutrons in 1934. Fermi concluded that his experiments had created new elements with 93 and 94 protons, which the group dubbed "ausonium and "hesperium. However, not all were convinced by Fermi's analysis of his results. The German chemist "Ida Noddack notably suggested in print in 1934 that instead of creating a new, heavier element 93, that "it is conceivable that the nucleus breaks up into several large fragments." However, Noddack's conclusion was not pursued at the time.
After the Fermi publication, "Otto Hahn, "Lise Meitner, and "Fritz Strassmann began performing similar experiments in "Berlin. Meitner, an Austrian Jew, lost her citizenship with the ""Anschluss", the occupation and annexation of Austria into "Nazi Germany in March 1938, but she fled in July 1938 to Sweden and started a correspondence by mail with Hahn in Berlin. By coincidence, her nephew "Otto Robert Frisch, also a refugee, was also in Sweden when Meitner received a letter from Hahn dated 19 December describing his chemical proof that some of the product of the bombardment of uranium with neutrons was "barium. Hahn suggested a bursting of the nucleus, but he was unsure of what the physical basis for the results were. Barium had an atomic mass 40% less than uranium, and no previously known methods of radioactive decay could account for such a large difference in the mass of the nucleus. Frisch was skeptical, but Meitner trusted Hahn's ability as a chemist. Marie Curie had been separating barium from radium for many years, and the techniques were well-known. According to Frisch:
Was it a mistake? No, said Lise Meitner; Hahn was too good a chemist for that. But how could barium be formed from uranium? No larger fragments than protons or helium nuclei (alpha particles) had ever been chipped away from nuclei, and to chip off a large number not nearly enough energy was available. Nor was it possible that the uranium nucleus could have been cleaved right across. A nucleus was not like a brittle solid that can be cleaved or broken; "George Gamow had suggested early on, and "Bohr had given good arguments that a nucleus was much more like a liquid drop. Perhaps a drop could divide itself into two smaller drops in a more gradual manner, by first becoming elongated, then constricted, and finally being torn rather than broken in two? We knew that there were strong forces that would resist such a process, just as the surface tension of an ordinary liquid drop tends to resist its division into two smaller ones. But nuclei differed from ordinary drops in one important way: they were electrically charged, and that was known to counteract the surface tension.
The charge of a uranium nucleus, we found, was indeed large enough to overcome the effect of the surface tension almost completely; so the uranium nucleus might indeed resemble a very wobbly unstable drop, ready to divide itself at the slightest provocation, such as the impact of a single neutron. But there was another problem. After separation, the two drops would be driven apart by their mutual electric repulsion and would acquire high speed and hence a very large energy, about 200 MeV in all; where could that energy come from? ...Lise Meitner... worked out that the two nuclei formed by the division of a uranium nucleus together would be lighter than the original uranium nucleus by about one-fifth the mass of a proton. Now whenever mass disappears energy is created, according to "Einstein's formula E= mc2, and one-fifth of a proton mass was just equivalent to 200 MeV. So here was the source for that energy; it all fitted!
In short, Meitner and Frisch had correctly interpreted Hahn's results to mean that the nucleus of uranium had split roughly in half. Frisch suggested the process be named "nuclear fission," by analogy to the process of living cell division into two cells, which was then called "binary fission. Just as the term nuclear "chain reaction" would later be borrowed from chemistry, so the term "fission" was borrowed from biology.
On 22 December 1938, Hahn and Strassmann sent a manuscript to "Naturwissenschaften reporting that they had discovered the element "barium after bombarding "uranium with "neutrons. Simultaneously, they communicated these results to Meitner in Sweden. She and Frisch correctly interpreted the results as evidence of nuclear fission. Frisch confirmed this experimentally on 13 January 1939. For proving that the "barium resulting from his bombardment of uranium with neutrons was the product of nuclear fission, Hahn was awarded the "Nobel Prize for Chemistry in 1944 (the sole recipient) "for his discovery of the fission of heavy nuclei". (The award was actually given to Hahn in 1945, as "the Nobel Committee for Chemistry decided that none of the year's nominations met the criteria as outlined in the will of Alfred Nobel." In such cases, the "Nobel Foundation's statutes permit that year's prize be reserved until the following year.)
News spread quickly of the new discovery, which was correctly seen as an entirely novel physical effect with great scientific—and potentially practical—possibilities. Meitner's and Frisch's interpretation of the discovery of Hahn and Strassmann crossed the Atlantic Ocean with "Niels Bohr, who was to lecture at "Princeton University. "I.I. Rabi and "Willis Lamb, two "Columbia University physicists working at Princeton, heard the news and carried it back to Columbia. Rabi said he told "Enrico Fermi; Fermi gave credit to Lamb. Bohr soon thereafter went from Princeton to Columbia to see Fermi. Not finding Fermi in his office, Bohr went down to the cyclotron area and found "Herbert L. Anderson. Bohr grabbed him by the shoulder and said: “Young man, let me explain to you about something new and exciting in physics.” It was clear to a number of scientists at Columbia that they should try to detect the energy released in the nuclear fission of uranium from neutron bombardment. On 25 January 1939, a Columbia University team conducted the first nuclear fission experiment in the United States, which was done in the basement of "Pupin Hall; the members of the team were "Herbert L. Anderson, "Eugene T. Booth, "John R. Dunning, "Enrico Fermi, "G. Norris Glasoe, and "Francis G. Slack. The experiment involved placing uranium oxide inside of an "ionization chamber and irradiating it with neutrons, and measuring the energy thus released. The results confirmed that fission was occurring and hinted strongly that it was the isotope "uranium 235 in particular that was fissioning. The next day, the Fifth Washington Conference on Theoretical Physics began in "Washington, D.C. under the joint auspices of the "George Washington University and the "Carnegie Institution of Washington. There, the news on nuclear fission was spread even further, which fostered many more experimental demonstrations.
During this period the Hungarian physicist "Leó Szilárd, who was residing in the United States at the time, realized that the neutron-driven fission of heavy atoms could be used to create a "nuclear chain reaction. Such a reaction using neutrons was an idea he had first formulated in 1933, upon reading Rutherford's disparaging remarks about generating power from his team's 1932 experiment using protons to split lithium. However, Szilárd had not been able to achieve a neutron-driven chain reaction with neutron-rich light atoms. In theory, if in a neutron-driven chain reaction the number of secondary neutrons produced was greater than one, then each such reaction could trigger multiple additional reactions, producing an exponentially increasing number of reactions. It was thus a possibility that the fission of uranium could yield vast amounts of energy for civilian or military purposes (i.e., "electric power generation or "atomic bombs).
Szilard now urged Fermi (in New York) and "Frédéric Joliot-Curie (in Paris) to refrain from publishing on the possibility of a chain reaction, lest the Nazi government become aware of the possibilities on the eve of what would later be known as "World War II. With some hesitation Fermi agreed to self-censor. But Joliot-Curie did not, and in April 1939 his team in Paris, including "Hans von Halban and "Lew Kowarski, reported in the journal Nature that the number of neutrons emitted with nuclear fission of 235U was then reported at 3.5 per fission. (They later corrected this to 2.6 per fission.) Simultaneous work by Szilard and "Walter Zinn confirmed these results. The results suggested the possibility of building "nuclear reactors (first called "neutronic reactors" by Szilard and Fermi) and even nuclear bombs. However, much was still unknown about fission and chain reaction systems.
""Chain reactions" at that time were a known phenomenon in chemistry, but the analogous process in nuclear physics, using neutrons, had been foreseen as early as 1933 by Szilárd, although Szilárd at that time had no idea with what materials the process might be initiated. Szilárd considered that neutrons would be ideal for such a situation, since they lacked an electrostatic charge.
With the news of fission neutrons from uranium fission, Szilárd immediately understood the possibility of a nuclear chain reaction using uranium. In the summer, Fermi and Szilard proposed the idea of a "nuclear reactor (pile) to mediate this process. The pile would use natural uranium as fuel. Fermi had shown much earlier that neutrons were far more effectively captured by atoms if they were of low energy (so-called "slow" or "thermal" neutrons), because for quantum reasons it made the atoms look like much larger targets to the neutrons. Thus to slow down the secondary neutrons released by the fissioning uranium nuclei, Fermi and Szilard proposed a graphite "moderator," against which the fast, high-energy secondary neutrons would collide, effectively slowing them down. With enough uranium, and with pure-enough graphite, their "pile" could theoretically sustain a slow-neutron chain reaction. This would result in the production of heat, as well as the creation of radioactive "fission products.
In August 1939, Szilard and fellow Hungarian refugees physicists "Teller and "Wigner thought that the Germans might make use of the fission chain reaction and were spurred to attempt to attract the attention of the United States government to the issue. Towards this, they persuaded German-Jewish refugee "Albert Einstein to lend his name to a letter directed to President "Franklin Roosevelt. The "Einstein–Szilárd letter suggested the possibility of a uranium bomb deliverable by ship, which would destroy "an entire harbor and much of the surrounding countryside." The President received the letter on 11 October 1939 — shortly after World War II began in Europe, but two years before U.S. entry into it. Roosevelt ordered that a scientific committee be authorized for overseeing uranium work and allocated a small sum of money for pile research.
In England, "James Chadwick proposed an atomic bomb utilizing natural uranium, based on a paper by "Rudolf Peierls with the mass needed for critical state being 30–40 tons. In America, J. Robert Oppenheimer thought that a cube of uranium deuteride 10 cm on a side (about 11 kg of uranium) might "blow itself to hell." In this design it was still thought that a moderator would need to be used for nuclear bomb fission (this turned out not to be the case if the fissile isotope was separated). In December, "Werner Heisenberg delivered a report to the German Ministry of War on the possibility of a uranium bomb. Most of these models were still under the assumption that the bombs would be powered by slow neutron reactions—and thus be similar to a reactor undergoing a "meltdown.
In Birmingham, England, Frisch teamed up with "Peierls, a fellow German-Jewish refugee. They had the idea of using a purified mass of the uranium isotope 235U, which had a "cross section just determined, and which was much larger than that of 238U or natural uranium (which is 99.3% the latter isotope). Assuming that the cross section for fast-neutron fission of 235U was the same as for slow neutron fission, they determined that a pure 235U bomb could have a critical mass of only 6 kg instead of tons, and that the resulting explosion would be tremendous. (The amount actually turned out to be 15 kg, although several times this amount was used in the actual uranium ("Little Boy) bomb). In February 1940 they delivered the "Frisch–Peierls memorandum. Ironically, they were still officially considered "enemy aliens" at the time. "Glenn Seaborg, "Joseph W. Kennedy, "Arthur Wahl, and Italian-Jewish refugee "Emilio Segrè shortly thereafter discovered 239Pu in the decay products of 239U produced by bombarding 238U with neutrons, and determined it to be a fissile material, like 235U.
The possibility of isolating uranium-235 was technically daunting, because uranium-235 and uranium-238 are chemically identical, and vary in their mass by only the weight of three neutrons. However, if a sufficient quantity of uranium-235 could be isolated, it would allow for a fast neutron fission chain reaction. This would be extremely explosive, a true "atomic bomb." The discovery that plutonium-239 could be produced in a nuclear reactor pointed towards another approach to a fast neutron fission bomb. Both approaches were extremely novel and not yet well understood, and there was considerable scientific skepticism at the idea that they could be developed in a short amount of time.
On June 28, 1941, the "Office of Scientific Research and Development was formed in the U.S. to mobilize scientific resources and apply the results of research to national defense. In September, Fermi assembled his first nuclear "pile" or reactor, in an attempt to create a slow neutron-induced chain reaction in uranium, but the experiment failed to achieve criticality, due to lack of proper materials, or not enough of the proper materials which were available.
Producing a fission chain reaction in natural uranium fuel was found to be far from trivial. Early nuclear reactors did not use isotopically enriched uranium, and in consequence they were required to use large quantities of highly purified graphite as neutron moderation materials. Use of ordinary water (as opposed to "heavy water) in nuclear reactors requires enriched fuel — the partial separation and relative enrichment of the rare 235U isotope from the far more common 238U isotope. Typically, reactors also require inclusion of extremely chemically pure "neutron moderator materials such as "deuterium (in "heavy water), "helium, "beryllium, or carbon, the latter usually as "graphite. (The high purity for carbon is required because many chemical impurities such as the "boron-10 component of natural "boron, are very strong neutron absorbers and thus "poison the chain reaction and end it prematurely.)
Production of such materials at industrial scale had to be solved for nuclear power generation and weapons production to be accomplished. Up to 1940, the total amount of uranium metal produced in the USA was not more than a few grams, and even this was of doubtful purity; of metallic beryllium not more than a few kilograms; and concentrated deuterium oxide ("heavy water) not more than a few kilograms. Finally, carbon had never been produced in quantity with anything like the purity required of a moderator.
The problem of producing large amounts of high purity uranium was solved by "Frank Spedding using the "thermite or ""Ames" process. "Ames Laboratory was established in 1942 to produce the large amounts of natural (unenriched) uranium metal that would be necessary for the research to come. The critical nuclear chain-reaction success of the "Chicago Pile-1 (December 2, 1942) which used unenriched (natural) uranium, like all of the atomic "piles" which produced the plutonium for the atomic bomb, was also due specifically to Szilard's realization that very pure graphite could be used for the moderator of even natural uranium "piles". In wartime Germany, failure to appreciate the qualities of very pure graphite led to reactor designs dependent on heavy water, which in turn was denied the Germans by Allied attacks in Norway, where "heavy water was produced. These difficulties—among many others— prevented the Nazis from building a nuclear reactor capable of criticality during the war, although they never put as much effort as the United States into nuclear research, focusing on other technologies (see "German nuclear energy project for more details).
In the United States, an all-out effort for making atomic weapons was begun in late 1942. This work was taken over by the "U.S. Army Corps of Engineers in 1943, and known as the Manhattan Engineer District. The top-secret "Manhattan Project, as it was colloquially known, was led by General "Leslie R. Groves. Among the project's dozens of sites were: "Hanford Site in Washington state, which had the first industrial-scale "nuclear reactors; "Oak Ridge, Tennessee, which was primarily concerned with "uranium enrichment; and "Los Alamos, in New Mexico, which was the scientific hub for research on bomb development and design. Other sites, notably the "Berkeley Radiation Laboratory and the "Metallurgical Laboratory at the University of Chicago, played important contributing roles. Overall scientific direction of the project was managed by the physicist "J. Robert Oppenheimer.
In July 1945, the first atomic explosive device, dubbed ""Trinity", was detonated in the New Mexico desert. It was fueled by plutonium created at Hanford. In August 1945, two more atomic devices – ""Little Boy", a uranium-235 bomb, and ""Fat Man", a plutonium bomb – were "used against the Japanese cities of Hiroshima and Nagasaki.
In the years after World War II, many countries were involved in the further development of nuclear fission for the purposes of nuclear reactors and nuclear weapons. The UK opened the first commercial nuclear power plant in 1956. By 2013, there were 437 reactors in 31 countries.
"Criticality in nature is uncommon. At three ore deposits at "Oklo in "Gabon, sixteen sites (the so-called "Oklo Fossil Reactors) have been discovered at which self-sustaining nuclear fission took place approximately 2 billion years ago. Unknown until 1972 (but postulated by "Paul Kuroda in 1956), when French physicist "Francis Perrin discovered the "Oklo Fossil Reactors, it was realized that nature had beaten humans to the punch. Large-scale natural uranium fission chain reactions, moderated by normal water, had occurred far in the past and would not be possible now. This ancient process was able to use normal water as a moderator only because 2 billion years before the present, natural uranium was richer in the shorter-lived fissile isotope 235U (about 3%), than natural uranium available today (which is only 0.7%, and must be enriched to 3% to be usable in light-water reactors).